Rolf Slotboom looks to be our earliest exit, he had been in a preflop raising war with another player and was a non-believer with when his opponent moved all in on an board. But his timing proved to be off as he was up against which made two pair on the turn and Slotboom couldn't catch a two-outer on the river. He was left with a paltry 50 chips which went in soon after and predictably, couldn't manage a comeback.
The kicker to make things even worse? According to Steve Frezer the tournament director, it was Rolf's own girlfriend who dealt the cards that sent him to the rail.